SAFETY DATA SHEET
Page 1 of 6
HFT-68129
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
1. PRODUCT & COMPANY IDENTIFICATION
1.1 Product Name:
CR2032 LITHIUM BUTTON CELL BATTERIES
1.2 Chemical Name:
Lithium Manganese Dioxide Battery
1.3 Synonyms:
P/N 68129
1.4 Trade Names:
Thunderbolt Magnum
1.5 Product Uses & Restrictions:
Battery
1.6 Distributor’s Name:
Harbor Freight Tools, Inc.
1.7 Distributor’s Address:
26541 Agoura Road, Calabasas, CA 91302 USA
1.8 Emergency Phone:
CHEMTREC: +1 (703) 527-3887 / +1 (800) 424-9300 (CCN 676687)
1.9 Business Phone / Fax:
+1 (800) 423-2567
2. HAZARDS IDENTIFICATION
2.1 Hazard Identification:
This product is classified as a HAZARDOUS SUBSTANCE and as DANGEROUS GOODS
according to the classification criteria of NOHSC: 1008 (2004) and ADG Code (Australia).
If handled properly, there are no known serious health risks. Inhalation, absorption & ingestion are
unlikely under normal conditions as the battery is hermetically sealed within the device. However,
if device is crushed, or compromised in a fire, contact with the lithium metal battery and material
may cause damage to eyes & skin tissue as well as the nose, throat, lungs & respiratory tract if
inhaled. Please strictly observe safety instructions.
The following statements apply to the contents of the lithium metal battery if it has been
compromised (e.g., opened, crushed, punctured). These statements do not apply to the
hermetically sealed device which has not been damaged or compromised.
DANGER! CONTACT WITH WATER RELEASES FLAMMABLE GASES WHICH MAY IGNITE
SPONTANEOUSLY. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY BE
HARMFUL IF SWALLOWED.
Hazard Statements
(H): H260 - In contact with water releases flammable gases which may ignite
spontaneously. H314 - Causes severe skin burns and eye damage. EU014 – Reacts violently
with water.
Precautionary Statements
(P): P223 – Keep away from any possible contact with water, because
of violent reaction and possible flash fire. P264 – Wash hands and exposed skin surfaces
thoroughly with warm water and soap after handling. P280 – Wear protective gloves/eye
protection/face protection. P301+P330+P331 – IF SWALLOWED: Rinse mouth. Do NOT induce
vomiting. P310 – Immediately call a Poison Control Center or doctor/physician. P370+P378 – In
case of fire: Use Lith-X powder, Class D fire extinguisher, Dry Lithium Chloride, or Graphite
Powder for extinction. P402+P404 – Store in a dry place. Store in a closed container. P501 –
Dispose of contents through a licensed treatment, storage, disposal facility (TSDF).
3. COMPOSITION & INGREDIENT INFORMATION
CHEMICAL NAME(S) CAS No. RTECS No.
EINECS No. %
EXPOSURE LIMITS IN AIR (mg/m
3
)
ACGIH NOHSC OSHA
OTHER
ppm ppm ppm
TLV STEL
ES-
TWA
ES-
STEL
ES-
PEAK PEL STEL IDLH
MANGANESE DIOXIDE
1313-13-9 OP0350000 215-202-6 15-40 (5) NA (5) NF NF (5) NA NA
Acute Tox. Oral 4; Acute Tox. Inh. 4; H302, H332
1,2-DIMETHOXYETHANE
110-71-4 KI1451000 NA 3-7 3 NA 3 NF NF NA NA NA
TETRAFLUOROETHYLENE
(TEFLON)
116-14-3 KX4025000 204-126-9 1-5 (10) NA (10) NF NF (15) NA NA
LITHIUM METAL
7439-93-2 OJ5540000 231-102-5 1-5 NA NA NF NF NF NA NA NA
Water React 1; Skin Corr. 1B; H260, H314
CARBON BLACK
1333-86-4 FF5800000 215-609-9 0.5-2.5 (3.5) NA (3.5) NF NF (3.5) NA NA
PROPYLENE CARBONATE
108-32-7 FF9650000 203-572-1 1-5 NA NA NF NF NF NA NA NA
Eye Irrit. 2B; H319
GRAPHITE
7782-42-5 MD9659600 231-955-3 0.5-1.5 (2) NA (2) NF NF NA NA NA
Eye Irrit. 2; STOT SE 3; H319, H335
LITHIUM PERCHLORATE
7791-03-9 NA 232-237-2 0.1-1 NA NA NF NF NF NA NA NA
Ox. Sol. 2; Skin Irrit. 2; Eye Irrit. 2B; STOT SE 3; H272, H315, H319, H335
SAFETY DATA SHEET
Page 2 of 6
HFT-68129
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
4. FIRST AID MEASURES
4.1 First Aid:
Device is hermetically sealed. Exposure to lithium battery component is not expected under normal conditions of use.
Ingestion
: Swallowing a battery can be harmful. 3 volt lithium coin batteries lodged in the esophagus should be
removed immediately. Leakage, chemical burns and potential perforation can occur within hours of
ingestion. Seek medical attention immediately. Have physician call the NATIONAL BATTERY INGESTION
HOTLINE for advice and follow-up at +1 (202) 625-3333 collect day or night.
Eyes
: Contents of an open battery can cause severe irritation. Splashes are not likely; however, if product gets
in the eyes, flush with copious amounts of lukewarm water seek immediate medical attention.
Skin
: Contents of an open battery can cause skin irritation. Remove contaminated clothing and flush affected
areas. Wash thoroughly with soap and water.
Inhalation
: Remove victim to fresh air at once. If breathing is difficult, administer oxygen. If breathing stops give
artificial respiration. Keep person warm, quiet and get medical attention.
4.2 Effects of Exposure:
Ingestion: Not anticipated under normal handling and use. Irritation to the internal/external mouth area may occur
following exposure to leaking battery.
Eyes
: Not anticipated under normal handling and use. If device is damaged, eye and mucous membrane
irritation may occur following exposure to leaking battery.
Skin
: Not anticipated under normal handling and use. Irritation may occur following exposure to leaking battery.
Inhalation
: Not anticipated. Respiratory irritation may occur if fumes are released due to an abundance of leaking
batteries.
4.3 Symptoms of Overexposure:
Ingestion: Not anticipated. Irritation may occur following exposure to leaking battery.
Eyes
: Not anticipated. If device is damaged, eye and mucous membrane irritation may occur following exposure
to a leaking battery.
Skin
: Not anticipated. Irritation may occur following exposure to leaking battery. Symptoms of skin
overexposure may include redness, itching, and irritation of affected areas.
Inhalation
: Not anticipated. Respiratory irritation may occur if fumes are released due to heat or an abundance of
leaking batteries. Respiratory irritation, headache, irritability may occur if fumes are released due to heat
or an abundance of leaking batteries.
4.4 Acute Health Effects:
Non-irritating when used as directed. No acute health effects reported by the manufacturer.
4.5 Chronic Health Effects:
Non-irritating when used as directed. No chronic health effects reported by the manufacturer.
4.6 Target Organs:
The manufacturer has not reported specific data.
4.7 Medical Conditions
Aggravated by Exposure:
An initial x-ray should be obtained promptly to determine battery
location. Batteries lodged in the esophagus should be removed
immediately since leakage, burns and perforation can occur as soon as
4-6 hours after ingestion.
HEALTH
1
FLAMMABILITY
0
PHYSICAL HAZARDS
1
PROTECTIVE EQUIPMENT
B
5. FIREFIGHTING MEASURES
5.1 Fire & Explosion Hazards:
As with any fire, wear self-contained breathing apparatus to avoid inhalation of hazardous
decomposition products (See Section 2). Water will cool the fire but may react with available lithium
in the batteries producing flammable hydrogen. DO NOT RECHARGE. As a typical sealed battery
they may rupture when exposed to excessive heat. Rupture may expose lithium to moisture causing
it to react or release flammable or corrosive materials. Do not accumulate undischarged batteries
together. In case of fire where lithium batteries are present, flood area with water or smother with a
Class D fire extinguisher appropriate for lithium metal, such as Lith-X. Virtually all fires involving
lithium batteries can be controlled by flooding with water. However, the contents of the battery will
react with water and form hydrogen gas. In a confined space, hydrogen gas can form an explosive
mixture. In this situation, smothering agents are recommended. A smothering agent will extinguish
burning lithium batteries. Emergency Responders should wear self-contained breathing apparatus.
Burning lithium manganese dioxide batteries produce toxic and corrosive lithium hydroxide fumes.
5.2 Extinguishing Methods:
Lith-X-Powder, Class D Fire Extinguisher, Dry Lithium Chloride, Graphite Powder.
Not flammable under normal conditions. However, battery will burn if involved in a fire. Call fire
department. Cool exterior of battery if exposed to fire to prevent rupture. The electrolyte vapors
generated by heat or fire are corrosive.
5.3 Firefighting Procedures:
DO NOT USE WATER, moist sand, CO
2
, class ABC or soda ash extinguisher. When water is used
hydrogen gas may be evolved which can form an explosive mixture with air. Keep containers cool
until well after the fire is out, do NOT use water. As in any fire, wear MSHA/NIOSH approved self-
contained breathing apparatus (pressure-demand) and full protective gear. Keep containers cool
until well after the fire is out. Use water spray to cool fire-exposed surfaces and to protect personal.
Fight fire upwind. Prevent runoff from fire control or dilution from entering sewers, drains, drinking
water supply, or any natural waterway. Firefighters must use full bunker gear including NIOSH-
approved positive pressure self-contained breathing apparatus to protect against potential hazardous
combustion or decomposition products and oxygen deficiencies.
SAFETY DATA SHEET
Page 3 of 6
HFT-68129
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
None under normal conditions. If the contents leak, observe the following instructions: Secure spill area and maximize
ventilation. Stop spill or leak at source if safely possible. Deny entry to all unprotected individuals. Individuals involved
in the cleanup must wear appropriate personal protective equipment to avoid breathing vapors or touching liquid.
Recover or cover with inert absorbent material and place into appropriate container(s) for disposal. If in water remove if
safe to do so. If necessary, dike well ahead of the spill to prevent runoff into drains, sewers or any natural waterway or
drinking supply. Spills are unlikely as the battery is enclosed hermetically sealed device.
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
DO NOT swallow, apply excessive force to the positive terminal, drop, weld the terminal or wire to the body of the battery
directly, short-circuit the battery, charge, forcibly discharge, heat, expose to open flame, disassemble, reverse the
positive and negative terminals when mounting, use different batteries together, touch any liquid that leaks from the
battery, or hold the battery for an extended period.
7.2 Storage & Handling:
Keep battery away from water. Never store in hot or very humid place. Storage and handling areas should be equipped
with proper containment to capture and neutralize spills.
7.3 Special Precautions:
Do not expose to excessive physical shock or vibration. Storage and use areas should be equipped with eyewash
stations and safety showers.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Exposure Limits:
ppm (mg/m
3
)
CHEMICAL NAME(S)
ACGIH NOHSC OSHA OTHER
TLV STEL
ES-
TWA
ES-
STEL
ES-
PEAK PEL STEL IDLH
MANGANESE DIOXIDE (5) NA (5) NF NF (5) NA NA
GRAPHITE (2) NA (2) NF NF NA NA NA
CARBON BLACK (3.5) NA (3.5) NF NF (3.5) NA NA
TEFLON (10) NA (10) NF NF (15) NA NA
1,2-DIMETHOXYETHANE 3 NA 3 NF NF NA NA NA
8.2
Ventilation & Engineering
Controls:
General mechanical (e.g., fans) or natural ventilation is sufficient when this product is in use. Ensure appropriate
decontamination equipment is available (e.g., sink, safety shower, eye-wash station). Upon completion of work activities
involving large quantities of this product (fluid), wash any exposed areas thoroughly with soap and water.
8.3 Respiratory Protection:
No special respiratory protection is required under typical circumstances of use or handling. In
instances where mist or vapors of this product are generated, and respiratory protection is needed,
use only protection authorized by 29 CFR §1910.134, applicable U.S. State regulations, or the
Canadian CAS Standard Z94.4-93 and applicable standards of Canadian Provinces, EC member
States, or Australia.
8.4 Eye Protection:
Avoid eye contact. Wear protective eyewear (e.g., safety glasses with side-shield) at all times when
handling this product. Contact lenses pose a special hazard; soft lenses may absorb and
concentrate irritants. Have suitable eye wash water available. Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
8.5 Hand Protection:
Use gloves constructed of chemical-resistant materials such as neoprene or heavy nitrile rubber if
frequent or prolonged contact is expected. If necessary, refer to U.S. OSHA 29 CFR §1910.138, the
appropriate standards of Canada, or the EU member states. Do not wear rings, watches or jewelry
that could entrap the material against the skin.
8.6 Body Protection:
No apron required when handling sealed undamaged battery. Where contact is likely corrosive-
resistant apron, clothing and boots. Protective clothing, if used, should include long-sleeves, apron,
boots and additional facial protection. If necessary, refer to appropriate standards of Canada, the EU
member states, or U.S. OSHA.
9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Appearance:
Hermetically sealed, metallic article.
9.2 Odor:
None for sealed device.
9.3 Odor Threshold:
NA
9.4 pH:
NA
9.5 Melting Point/Freezing Point:
NA
9.6 Initial Boiling Point/Boiling
Range:
NA
9.7 Flashpoint:
NA
9.8 Upper/Lower Flammability
Limits:
NA
9.9 Vapor Pressure:
NA
9.10 Vapor Density:
NA
9.11 Relative Density:
2.0-3.0
9.12 Solubility:
Insoluble
9.13 Partition Coefficient (log P
ow
):
NA
9.14 Autoignition Temperature:
NA
SAFETY DATA SHEET
Page 4 of 6
HFT-68129
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
9. PHYSICAL & CHEMICAL PROPERTIES – cont’d
9.15 Decomposition Temperature:
NA
9.16 Viscosity:
NA
9.17 Other Information:
NA
10. STABILITY & REACTIVITY
10.1 Stability:
Stable under normal conditions; unstable with heat or contamination or if broken or leaking.
10.2 Hazardous Decomposition
Products:
Sulfur dioxide, hydrogen chloride, hydrogen.
10.3 Hazardous Polymerization:
Will not occur.
10.4 Conditions to Avoid:
Prolonged overcharge; sources of ignition. Excessive physical shock and vibration. Contact with organic materials,
combustibles, strong reducing agents, strong oxidizers and humidity.
10.5 Incompatible Substances:
Contact with organic materials, strong reducing agents, strong oxidizers, water and excessive humidity.
11. TOXICOLOGICAL INFORMATION
11.1 Routes of Entry: Inhalation:
NO
Absorption:
NO
Ingestion:
YES
11.2 Toxicity Data:
This product has NOT been tested on animals to obtain toxicology data. Toxicology data, found in scientific literature, is
available for some of the components of the product and is presented below:
Manganese Dioxide
: LD
50
(oral, rat): > 3,478 mg/kg;
1,2-Dimethoxyethane
: LD
Lo
(oral, rat): 1,000 mg/kg, LC
Lo
(inh-6h, rat): 63 g/m
3
Propylene Carbonate
: LD
50
(oral, rat): 29,100 uL/kg; LD
50
(dermal, rabbit):> 20 mL/kg; LC
50
(inh, rat): > 5 g/m
3
11.3 Acute Toxicity:
See Section 4.4.
11.4 Chronic Toxicity:
See Section 4.5.
11.5 Suspected Carcinogen:
Carbon Black is listed as IARC Group 2B (Possibly carcinogenic to humans); CA65 (cancer).
11.6 Reproductive Toxicity:
This product is not reported to produce reproductive toxicity in humans.
Mutagenicity:
This product is not reported to produce mutagenic effects in humans.
Embryotoxicity:
This product is not reported to produce embryotoxic effects in humans.
Teratogenicity:
This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity:
This product is not reported to cause reproductive effects in humans.
11.7 Irritancy of Product:
See Section 4.3
11.8 Biological Exposure Indices:
NE
11.9 Physician Recommendations:
Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
There are no specific data available for this product.
12.2 Effects on Plants & Animals:
There are no specific data available for this product.
12.3 Effects on Aquatic Life:
There are no specific data available for this product.
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in accordance with federal, state, provincial and local regulations.
13.2 Special Considerations:
NA
14. TRANSPORTATION INFORMATION
The basic description (ID Number, proper shipping name, hazard class & division, packing group) is shown for each mode of transportation. Additional
descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
UN3090, LITHIUM METAL BATTERIES, 9, II (NET WGT ≤ 5.0 kg)
14.2 IATA (AIR):
UN3090, LITHIUM METAL BATTERIES, 9, II – FORBIDDEN FOR TRANSPORT ABOARD
PASSENGER AIRCRAFT.
See Section II of Packing Instruction 968. *
14.3 IMDG (OCN):
UN3090, LITHIUM METAL BATTERIES, 9, II (NET WGT ≤ 5.0 kg)
See IMDG Code Special Provision 188
14.4 TDGR (Canadian GND):
UN3090, LITHIUM METAL BATTERIES, 9, II (NET WGT ≤ 5.0 kg)
14.5 ADR/RID (EU):
UN3090, LITHIUM METAL BATTERIES, 9, II (NET WGT ≤ 5.0 kg)
14.6 SCT (MEXICO):
UN3090, BATERIAS DE LITIA, 9, II (NET WGT ≤ 5.0 kg)
14.7 ADGR (AUS):
UN3090, LITHIUM METAL BATTERIES, 9, II (NET WGT ≤ 5.0 kg)
* Each package must be labeled with a Cargo Aircraft Only label in addition to the lithium battery handling label. Additional marking is required for lithium metal batteries
transported by all modes of transport in the United States or to Canada. See also 49 CFR § 173.185 (c)(iii).
LITHIUM METAL BATTERIES ARE FORBIDDEN FOR TRANSPORT ABOARD PASSENGER AIRCRAFT
SAFETY DATA SHEET
Page 5 of 6
HFT-68129
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
15. REGULATORY INFORMATION
15.1 SARA Reporting
Requirements:
This product does not contain any substances subject to SARA Title III, section 313 reporting requirements.
15.2 SARA Threshold Planning
Quantity:
There are no specific Threshold Planning Quantities for the components of this product.
15.3 TSCA Inventory Status:
The components of this product are listed on the TSCA Inventory or are otherwise exempt.
15.4 CERCLA Reportable Quantity
(RQ):
NA
15.5 Other Federal Requirements:
Manganese (and its compounds) is listed as a Hazardous Air Pollutant (HAP). Manganese (and its compounds) is listed
as Toxic Pollutants under the Clean Water Act (CWA). None of the ingredients are listed as Priority Pollutants under the
Clean Water Act (CWA). This product does not contain any Class 1 or Class 2 ozone depletors.
15.6 Other Canadian Regulations:
This product has been classified according to the hazard criteria of the Controlled Products
Regulations (CPR) and the SDS contains all of the information required by the CPR. The
components of this product are listed on the DSL/NDSL. None of the components of this product
are listed on the Priorities Substances List. WHMIS D2B (Other Toxic Effects)
15.7 State Regulatory Information:
Carbon Black is listed in the following state criteria lists: California Proposition 65 (CA65), Massachusetts Hazardous
Substances List (MA), Minnesota Hazardous Substances List (MN), New Jersey Right-to-Know List (NJ), and
Pennsylvania Right-to-Know List (PA).
Lithium
is found on the following state criteria lists: FL, MA, NJ and PA.
Propylene Carbonate
is found on the following state criteria lists: NJ and PA.
1,2-Dimethoxyethane
is found on the following state criteria lists: FL, MA and PA.
No other ingredients in this product, present in a concentration of 1.0% or greater, are listed on any of the following state
criteria lists: California Proposition 65 (CA65), Delaware Air Quality Management List (DE), Florida Toxic Substances
List (FL), Massachusetts Hazardous Substances List (MA), Michigan Critical Substances List (MI), Minnesota Hazardous
Substances List (MN), New Jersey Right-to-Know List (NJ), New York Hazardous Substances List (NY), Pennsylvania
Right-to-Know List (PA), Washington Permissible Exposures List (WA), Wisconsin Hazardous Substances List (WI).
WARNING: This product contains a substance(s) known to the State of California to cause cancer, birth defects or other
reproductive harm. California law requires this warning be given to customers in the State of California.
NOTE: Perchlorate Material - special handling may apply. See www.dtsc.ca.gov/hazardouswaste/perchlorate.
15.8 Other Requirements:
The primary components of this product are not listed in Annex I of EU Directive 67/548/EEC:
Harmful (Xn). Risk Phrases
(R): 65 – Harmful may cause lung damage if swallowed. Safety
Phrases (S): 2-62 - Keep away from children. If swallowed, do not induce vomiting: seek medical
advice immediately and show this container or label where possible.
16. OTHER INFORMATION
16.1 Other Information:
DANGER: IN CONTACT WITH WATER RELEASES FLAMMABLE GASES WHICH MAY IGNITE SPONTANEOUSLY.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY BE HARMFUL IF SWALLOWED. Keep away from any
possible contact with water, because of violent reaction and possible flash fire. Wash hands and exposed skin surfaces
thoroughly with warm water and soap after handling. Wear protective gloves/eye protection/face protection. IF
SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a Poison Control Center or doctor/physician.
In case of fire: Use Lith-X powder, Class D fire extinguisher, Dry Lithium Chloride, or Graphite Powder for extinction.
P402+P404 – Store in a dry place. Store in a closed container. KEEP OUT OF THE REACH OF CHILDREN.
WARNING: This product contains a substance(s) known to the State of California to cause cancer, birth defects or other
reproductive harm
16.2 Terms & Definitions:
See last page of this Safety Data Sheet.
16.3 Disclaimer:
This Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR §1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Harbor Freight
Tools USA, Inc.’s knowledge, the information contained herein is reliable and accurate as of this date; however,
accuracy, suitability or completeness is not guaranteed and no warranties of any type, either expressed or implied, are
provided. The information contained herein relates only to the specific product(s). If this product(s) is combined with
other materials, all component properties must be considered. Data may be changed from time to time. Be sure to
consult the latest edition.
16.4 Prepared for:
Harbor Freight Tools USA, Inc.
26541 Agoura Road
Calabasas, CA 91302 USA
Tel: +1 (805) 388-1000
http://www.harborfreight.com/
16.5 Prepared by:
ShipMate, Inc.
P.O. Box 787
Sisters, Oregon 97759-0787 USA
Tel: +1 (310) 370-3600
Fax: +1 (310) 370-5700
http://www.shipmate.com
SAFETY DATA SHEET
Page 6 of 6
HFT-68129
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a SDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
CAS No. Chemical Abstract Service Number
EXPOSURE LIMITS IN AIR:
ACGIH American Conference on Governmental Industrial Hygienists
C Ceiling Limit
ES Exposure Standard (Australia)
IDLH Immediately Dangerous to Life and Health
OSHA U.S. Occupational Safety and Health Administration
PEL Permissible Exposure Limit
STEL Short-Term Exposure Limit
TLV Threshold Limit Value
TWA Time Weighted Average
FIRST AID MEASURES:
CPR Cardiopulmonary resuscitation - method in which a person whose heart has
stopped receives manual chest compressions and breathing to circulate blood
and provide oxygen to the body.
HMIS-III HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
0 Minimal Hazard
HEALTH
1 Slight Hazard
FLAMMABILITY
2 Moderate Hazard
PHYSICAL HAZARDS
3 Severe Hazard
PERSONAL PROTECTION
4 Extreme Hazard
PERSONAL PROTECTION RATINGS:
A
G
B
H
C
I
D
J
E
K
F
X
Consult your supervisor or SOPs fo
r
special handling directions.
Safety Glasses
Splash Goggles
Face Shield &
Protective Eyewear
Gloves
Boots
Synthetic Apron
Protective Clothing
& Full Suit
Dust Respirator
Full Face Respirator
Dust & Vapor Half-
Mask Respirator
Full Face
Respirator
Airline Hood/Mask
or SCBA
OTHER STANDARD ABBREVIATIONS:
ML Maximum Limit
mg/m3 milligrams per cubic meter
NA Not Available
ND Not Determined
NE Not Established
NF Not Found
NR No Results
ppm parts per million
SCBA Self-Contained Breathing Apparatus
NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
FLAMMABILITY LIMITS IN AIR:
Autoignition
Temperature
Minimum temperature required to initiate combustion in air with no other
source of ignition
LEL Lower Explosive Limit - lowest percent of vapor in air, by volume, that will
explode or ignite in the presence of an ignition source
UEL Upper Explosive Limit - highest percent of vapor in air, by volume, that will
explode or ignite in the presence of an ignition source
HAZARD RATINGS:
0 Minimal Hazard
1 Slight Hazard
2 Moderate Hazard
3 Severe Hazard
4 Extreme Hazard
ACD Acidic
ALK Alkaline
COR Corrosive
W Use No Water
OX Oxidizer
TREFOIL Radioactive
TOXICOLOGICAL INFORMATION:
LD
50
Lethal Dose (solids & liquids) which kills 50% of the exposed animals
s
LC
50
Lethal concentration (gases) which kills 50% of the exposed animal
ppm Concentration expressed in parts of material per million parts
TD
lo
Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
TD
lo
, LD
lo
, & LD
o
or
TC, TC
o
, LC
lo
, & LC
o
Lowest dose (or concentration) to cause lethal or toxic effects
IARC International Agency for Research on Cancer
NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
TL
m
Median threshold limit
log K
OW
or log K
OC
Coefficient of Oil/Water Distribution
REGULATORY INFORMATION:
WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
TC Transport Canada
EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
NOHSC National Occupational Health and Safety Commission (Australia)
NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
WGK Wassergefährdungsklassen (German Water Hazard Class)
HMIS-III National Paint & Coatings Association Hazardous Materials Identification System
WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION (WHMIS) SYSTEM:
Class A Class B Class C Class D1 Class D2 Class D3 Class E Class F
Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive
EC (67/548/EEC) INFORMATION:
C E F N O T Xi Xn
Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
CLP/GHS (1272/2008/EC) PICTOGRAMS:
GHS01 GHS02 GHS03 GHS04 GHS05 GHS06 GHS07 GHS08 GHS09
Explosive Flammable Oxidizer Pressurized Corrosive Toxic
Harmful
Irritating
Health
Hazard
Environment
