SAFETY DATA SHEET
Page 1 of 6
HFT-97861
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
1. PRODUCT & COMPANY IDENTIFICATION
1.1 Product Name:
AAA NiMH RECHARGEABLE BATTERIES
1.2 Chemical Name:
Nickel Metal Hydride Battery
1.3 Synonyms:
P/N 97861
1.4 Trade Names:
Thunderbolt Magnum
1.5 Product Uses & Restrictions:
Electric Storage Battery
1.6 Distributor’s Name:
Harbor Freight Tools USA, Inc.
1.7 Distributor’s Address:
26541 Agoura Road, Calabasas, CA 91302 USA
1.8 Emergency Phone:
CHEMTREC: +1 (703) 527-3887 / +1 (800) 424-9300 (CCN 676687)
1.9 Business Phone / Fax:
+1 (805) 388-1000
2. HAZARDS IDENTIFICATION
2.1 Hazard Identification:
This product is classified as a HAZARDOUS SUBSTANCE and as DANGEROUS GOODS
according to the classification criteria of [NOHSC: 1088 (2004)] and ADG Code (Australia).
The materials contained in this product may only represent the hazards below if the if the integrity
of the battery is compromised, physically or electrically abused:
DANGER! CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. HARMFUL IF SWALLOWED.
Hazard Statements
(H): H314 – Causes severe skin burns and eye damage. H302 – Harmful if
swallowed. H411 – Toxic to aquatic life with long lasting effects.
Precautionary Statements
(P): P260 – Do not breathe fumes/mist/vapor/spray. P264 – Wash
hands and exposed skin areas with soap and warm water thoroughly after handling. P273 – Avoid
release to the environment. P280 – Wear protective gloves/eye protection. P301+P330+P331 – IF
SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair):
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P363 -
Wash contaminated clothing before reuse. P304+P340 – IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. P310 – Immediately call a POISON
CENTER or doctor/physician. P305+P351+P338 – IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses if present and easy to do – continue rinsing. P405 – Store
locked up. P501 – Dispose of contents/container to licenses treatment, storage and disposal facility
(TSDF).
3. COMPOSITION & INGREDIENT INFORMATION
CHEMICAL NAME(S) CAS No. RTECS No.
EINECS No. %
EXPOSURE LIMITS IN AIR (mg/m
3
)
ACGIH NOHSC OSHA
OTHER
ppm ppm ppm
TLV STEL
ES-
TWA
ES-
STEL
ES-
PEAK PEL STEL IDLH
POSITIVE ELECTRODE:
30-60
NICKEL HYDROXIDE
12054-48-7 QR7040000 235-008-5 10 NA NF NF NF 5 NA NA
Acute Tox. 4; Skin Irrit. 2; Skin Sens. 1; Acute Tox. 4; Resp. Sens. 1; Muta. 2; Carc. 1A; Repr. 1B; STOT RE 1; Aquatic Acute 1; Aquatic
chronic 1; H302, H315, H317, H332, H334, H341, H350, H360, H372, H400, H410H351
NEGATIVE ELECTRODE:
30-60
MISCH METAL ALLOY
LANTHANUM
7439-91-0 NA 231-099-0 NA NA NF NF NF NA NA NA
CERIUM
7440-45-1 FK485000 231-154-9 NA NA NF NF NF NA NA NA
Flam. Sol. 1; H228
NEODYMIUM
7440-00-8 QO8575000 231-109-3 NA NA NF NF NF NA NA NA
PRASEODYMIUM
7440-10-0 NA 231-120-3 NA NA NF NF NF NA NA NA
Pyr. Sol. 1; H250
NICKEL METAL ALLOY
NICKEL
7440-02-0 QR5950000 231-111-4 30-60 1.5 NA 1 NA NA 1 NA 10
Skin Sens. 1, Carc. 2, CTOT RE 1, Aquatic Chronic 3, H317, H351, H372, H412
COBALT
7440-48-4 GF8750000 231-158-0 (.02) NA (.05) NA NA (.01) NA NA DUST
Skin Sens. 1, Resp. Sens. 1, Aquatic Chronic 4; H317, H334, H413
MANGANESE
7439-96-5 OO9275000 231-105-1 5 NA 1 NF 3 5 NA NA FUME
ALUMINUM
7429-90-5 BD0330000 231-072-3 10 NA 5 NF NF 10 15 5 RESP FRAC
Pyr. Sol. 1, Water React. 2; H250, H261
ZINC
7440-66-6 ZG8600000 231-175-3 15-40 NA NA NF NF NF NA NA NA
Aquatic Acute 1; Aquatic Chronic 1; H400, H410
ELECTROLYTE:
7-13
POTASSIUM HYDROXIDE
1310-58-3 TT2100000 215-181-3 2 NA 2 NF NF NE NA NA
Acute Tox. 4, Skin Corr. 1A
SODIUM HYDROXIDE
1310-73-2 WB4900000 215-185-5 2 NA 2 NF NF 2 NA 10
Skin Corr. 1A; H314
LITHIUM HYDROXIDE
1310-65-2 OJ6307070 215-183-4 NA NA NF NF NF NA NA NA
Acute Tox. 4, Skin Corr. 1B
SAFETY DATA SHEET
Page 2 of 6
HFT-97861
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
4. FIRST AID MEASURES
4.1 First Aid:
Ingestion: Give large quantities of water, but do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Contact the nearest Poison Control Center or local emergency telephone number for
assistance and instructions. Seek immediate medical attention. If vomiting occurs spontaneously, keep
victim’s head lowered (forward) to reduce the risk of aspiration.
Eyes
: If product gets in the eyes, flush eyes thoroughly with copious amounts of water for at least 15 minutes,
holding eyelid(s) open to ensure complete flushing. If the eyes or face become swollen during or following
use, consult a physician or emergency room immediately.
Skin
: If an open battery cell: Remove contaminated clothing and wash affected areas with soap and water. If
discomfort persists and/or the skin reaction worsens, contact a physician immediately. Do not wear
contaminated clothing until after it has been properly cleaned.
Inhalation
: Remove victim to fresh air at once. Under extreme conditions, if breathing stops, perform artificial
respiration. Seek immediate medical attention.
4.2 Effects of Exposure:
Eyes: Severe irritation, burns, cornea damage, blindness. Nickel compounds may cause irritation.
Skin
: Severe irritation, burns, and ulceration if open battery cell comes into contact with skin.
Ingestion
: May cause severe irritation of mouth, throat, esophagus, and stomach. Acute ingestion of lead
compounds may cause abdominal pain, nausea, vomiting, diarrhea, and severe cramping. This may lead
rapidly to systemic toxicity.
Inhalation
: Breathing of vapors or mists may cause severe respiratory irritation. Inhalation of fumes may cause
irritation of upper respiratory tract and lungs.
4.3 Symptoms of Overexposure:
Ingestion: Severe discomfort, nausea, vomiting and headache. Symptoms of nickel toxicity include headache,
fatigue, abdominal pain, loss of appetite, muscular aches and weakness, sleep disturbances, and
irritability.
Eyes
: Severe irritation, redness, and watering, damage to cornea and possible blindness.
Skin
: Severe skin irritation, red, itching skin, burns and ulceration, if open battery cell comes into contact with
skin.
Inhalation
: May cause irritation to the upper respiratory system. Overexposure to sprays or mists may cause chemical
pneumonitis.
4.4 Acute Health Effects:
Hazardous exposure can occur only when product is heated above the melting point, oxidized or otherwise processed or
damaged to create dust, vapor, or fume.
4.5 Chronic Health Effects:
NA
4.6 Target Organs:
Eyes, Skin, Respiratory System
4.7 Medical Conditions
Aggravated by Exposure:
Overexposure to electrolyte mist may cause lung damage and
aggravate pulmonary conditions. Contact of electrolyte (water and
hydroxide solution) with skin may aggravate skin diseases such as
eczema and contact dermatitis. Contact of electrolyte (water and metal
hydroxide solution) with eyes may damage cornea and/or cause
blindness.
HEALTH
2
FLAMMABILITY
1
PHYSICAL HAZARDS
1
PROTECTIVE EQUIPMENT
B
EYES SKIN
5. FIREFIGHTING MEASURES
5.1 Fire & Explosion Hazards:
This material can burn but will not readily ignite. However, if involved in a fire, this product may
decompose at high temperatures to form toxic gases (e.g., CO, CO
2,
Hydrocarbons).
5.2 Extinguishing Methods:
CO
2
, Dry Chemical, Alcohol Foam. Use water spray to cool containers.
5.3 Firefighting Procedures:
In case of fire where nickel metal hydride batteries are present, apply a smothering agent such as
METL-X, sand, dry grand dolomite, or soda ash, or flood the area with water .A smothering agent will
extinguish burning nickel metal hydride batteries. Water may not extinguish burning batteries but will
cool the adjacent batteries can be controlled with water. When water is used, however, hydrogen
gas may evolve. In a confined space, hydrogen gas can form an explosive mixture. In this situation,
smothering agents are recommended. Fire fighters should wear self-contained breathing apparatus.
Burning nickel metal hydride batteries can produce toxic fumes including oxides of nickel, cobalt,
aluminum, manganese, lanthanum, cerium, neodymium, and praseodymium.
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective
Equipment, including protective gloves and eyewear. Plastic or rubber gloves, respirator, eye/face protection and
chemical-resistant apron may be required for clean-up of large spills.
Small Spills
: Wear appropriate protective equipment including gloves and protective eyewear. Use a non-combustible
material such as vermiculite or sand to soak up the product and place into a container for later disposal. Do not use
water or a material such as “speedy dry” to soak up material. Sweep up material using non-sparking materials (e.g.,
plastic brooms, shovels, dustpans) and place into a plastic container or plastic liner within another container.
Large Spills
: Keep incompatible materials away from spill. Stay upwind and away from spill or release. Isolate
immediate hazard area and keep unauthorized personnel out of area. Stop spill or release if it can be done with minimal
risk. Wear appropriate protective equipment including respiratory protection as conditions warrant. Recover as much
free liquid as possible and collect in alkali-resistant container. Use absorbent to pick up residue. Keep spills and cleaning
runoffs out of drains, municipal sewers and open bodies of water.
SAFETY DATA SHEET
Page 3 of 6
HFT-97861
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Do not eat, drink or smoke when handling this product. Handle as to avoid puncturing container(s).
7.2 Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans) away from heat and direct
sunlight. Keep away from incompatible substances. Protect containers from physical damage. Storage and handling
areas should have equipment to capture and neutralize spills.
7.3 Special Precautions:
NA
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Exposure Limits:
ppm (mg/m
3
)
CHEMICAL NAME(S)
ACGIH NOHSC OSHA OTHER
TLV STEL ES-TWA ES-STEL ES-PEAK PEL STEL IDLH
NICKEL HYDROXIDE
10 NA NF NF NF 5 NA NA
NICKEL
1.5 NA 1 NA NA 1 NA 10
COBALT
(.02) NA (.05) NA NA (.01) NA NA
MANGANESE
5 NA 1 NF 3 5 NA NA
SODIUM HYDROXIDE
2 NA 2 NF NF 2 NA 10
POTASSIUM HYDROXIDE
2 NA 2 NF NF NE NA NA
8.2
Ventilation & Engineering
Controls:
Use local or general exhaust ventilation to effectively remove and prevent buildup of dusts generated from the use of this
product. Ensure appropriate decontamination equipment is available (e.g., sink, safety shower, eye-wash station).
8.3 Respiratory Protection:
No special respiratory protection is required under typical circumstances of use or handling. If
necessary, use only respiratory protection authorized per U.S. OSHA's requirement in 29 CFR
§1910.134, or applicable U.S. state regulations, or the appropriate standards of Canada, its
provinces, EU member states, or Australia.
8.4 Eye Protection:
Wear protective eyewear (e.g., safety glasses with side-shield) at all times when handling this
product. Always use protective eyewear when cleaning spills or leaks. Contact lenses pose a
special hazard; soft lenses may absorb and concentrate irritants. Have suitable eye wash water
available. Use equipment for eye protection tested and approved under appropriate government
standards such as NIOSH (US) or EN 166(EU).
8.5 Hand Protection:
Use gloves constructed of chemical-resistant materials such as neoprene or heavy nitrile rubber if
frequent or prolonged contact is expected. If necessary, refer to U.S. OSHA 29 CFR §1910.138, the
appropriate standards of Canada, or the EU member states.
8.6 Body Protection:
Avoid prolonged and/or repeated skin contact. Use clean and impervious protective clothing (e.g.,
neoprene or Tyvek
®
) if splashing or spraying conditions are present. Protective clothing should
include long-sleeves, apron, boots and additional facial protection. If necessary, refer to appropriate
standards of Canada, the EU member states, or U.S. OSHA.
9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Appearance:
Grayish, greenish color (positive electrode).
9.2 Odor:
Electrolyte is clear liquid with sharp pungent odor.
9.3 Odor Threshold:
NA
9.4 pH:
> 12 (electrolyte).
9.5 Melting Point/Freezing Point:
Melting point of misch metal alloy begins at 995°F (manganese).
9.6 Initial Boiling Point/Boiling
Range:
Boiling point of electrolyte is 212 °F (100 °C) (water).
9.7 Flashpoint:
259 °C (498 °F) - Hydrogen
9.8 Upper/Lower Flammability
Limits:
NA
9.9 Vapor Pressure:
11 mm Hg @ 77 °F
9.10 Vapor Density:
NA
9.11 Relative Density:
< 1.3 (water = 1.0)
9.12 Solubility:
Electrolyte: 100% soluble in water
9.13 Partition Coefficient (log P
ow
):
NA
9.14 Autoignition Temperature:
NA
9.15 Decomposition Temperature:
NA
9.16 Viscosity:
NA
9.17 Other Information:
NA
10. STABILITY & REACTIVITY
10.1 Stability:
Stable under normal conditions; unstable with heat or contamination.
10.2 Hazardous Decomposition
Products:
Metal hydroxides (e.g., Ni(OH)
2
, Mn(OH)
2
, etc.) and metal oxides (MnO, NiO, etc.) may form if involved in a fire.
10.3 Hazardous Polymerization:
Will not occur.
10.4 Conditions to Avoid:
Open flames, sparks, high heat, incompatible substances and direct sunlight.
10.5 Incompatible Substances:
Avoid extreme heat and ignition sources. Store away from oxidizers. Do not exceed rated capacity.
SAFETY DATA SHEET
Page 4 of 6
HFT-97861
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
11. TOXICOLOGICAL INFORMATION
11.1 Routes of Entry: Inhalation:
NO
Absorption:
YES
Ingestion:
YES
11.2 Toxicity Data:
This product has NOT been tested on animals to obtain toxicology data. Toxicology data, found in scientific literature, is
available for some of the components of the product, but is not presented in this document.
11.3 Acute Toxicity:
See Section 4.4
11.4 Chronic Toxicity:
See Section 4.5
11.5 Suspected Carcinogen:
Nickel metal and its compounds are suspected carcinogens; however, the acute and chronic effects of nickel alloys are
not known. Nickel
(metal) is a suspected carcinogen, IARC Group 2B, NTP 97-2. There are no known chronic health
effects for nickel metal alloys.
11.6 Reproductive Toxicity:
This product is not reported to cause reproductive effects in humans.
Mutagenicity:
This product is not reported to produce mutagenic effects in humans.
Embryotoxicity:
This product is not reported to produce embryotoxic effects in humans.
Teratogenicity:
This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity:
This product is not reported to cause reproductive effects in humans.
11.7 Irritancy of Product:
The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) upon prolonged or repeated exposure.
11.8 Biological Exposure Indices:
May cause damage to organs through prolonged or repeated exposure.
11.9 Physician Recommendations:
Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
There are no specific data available for this product.
12.2 Effects on Plants & Animals:
There are no specific data available for this product.
12.3 Effects on Aquatic Life:
There are no specific data available for this product.
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in accordance with federal, state, provincial and local regulations.
13.2 Special Considerations:
NA
14. TRANSPORTATION INFORMATION
The basic description (ID Number, proper shipping name, hazard class & division, packing group) is shown for each mode of transportation. Additional
descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED
14.2 IATA (AIR):
UN3496, BATTERIES, NICKEL-METAL HYDRIDE, 9
14.3 IMDG (OCN):
UN3496, BATTERIES, NICKEL-METAL HYDRIDE, 9
14.4 TDGR (Canadian GND):
NOT REGULATED
14.5 ADR/RID (EU):
NOT REGULATED
14.6 SCT (MEXICO):
NOT REGULATED
14.7 ADGR (AUS):
NOT REGULATED
15. REGULATORY INFORMATION
15.1 SARA Reporting
Requirements:
This product contains Nickel Hydroxide, Nickel, Magnesium, Aluminum, Sodium Hydroxide, which are subject to the
reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Nickel
, Cobalt, Manganese (metals), and
Aluminum
(fumes and dusts) are subject to SARA Title 313 (EPCRA).
15.2 SARA Threshold Planning
Quantity:
This product does not contain any substances with a SARA threshold planning quantity.
15.3 TSCA Inventory Status:
The components of this product are listed on the TSCA inventory or are otherwise exempt.
15.4 CERCLA Reportable Quantity
(RQ):
Nickel Hydroxide: 4.5 kg (10 lbs); Nickel: 45.4 kg (100 lbs); Potassium Hydroxide: 454kg (1000 lbs); Sodium Hydroxide:
454 kg (1000 lbs).
15.5 Other Federal Requirements:
Nickel Hydroxide (listed as Nickel compounds), Nickel is listed as a hazardous air pollutant (HAP). Nickel Hydroxide,
Potassium Hydroxide
and Sodium Hydroxide are listed as a Hazardous Substance under the CWA. Nickel Hydroxide is
listed as a Toxic Pollutant under the Clean Water Act. Nickel
is listed as a Priority Pollutant under the Clean Water Act.
Nickel
is listed as a Toxic Pollutant under the Clean Water Act.
15.6 Other Canadian Regulations:
This product has been classified according to the hazard criteria of the Controlled Products
Regulations (CPR) and the SDS contains all of the information required by the CPR. The
components of this product are listed on the DSL/NDSL. None of the components of this product
are listed on the Priorities Substances List. WHMIS E, D2B (Corrosive, Other Toxic Effects)
SAFETY DATA SHEET
Page 5 of 6
HFT-97861
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
15. REGULATORY INFORMATION – cont’d
15.7 State Regulatory Information:
Nickel Hydroxide is found on the following state criteria lists: California Proposition 65 (CA65), Massachusetts
Hazardous Substances List (MA), Minnesota Hazardous Substances List (MN), New Jersey Right-to-Know List (NJ) and
Pennsylvania Right-to-Know List (PA).
Nickel
is found on the following state criteria lists: CA65, MA, MN, NJ and PA.
Aluminum
is found on the following state criteria lists: MA, MN, NJ and PA.
Potassium Hydroxide
is found on the following state criteria lists: Florida Toxic Substances List (FL), MA, MN, NJ, PA
and Washington Permissible Exposures List (WA).
Sodium Hydroxide
is found on the following state criteria lists: FL, MA MN, NJ, PA and WA.
Lithium Hydroxide
is found on the following state criteria lists: MN.
NOTE: This product contains a substance(s) known to the State of California to cause cancer, birth defects or other
reproductive harm.
No other ingredients in this product, present in a concentration of 1.0% or greater, are listed on any of the following state
criteria lists: California Proposition 65 (CA65), Delaware Air Quality Management List (DE), Florida Toxic Substances
List (FL), Massachusetts Hazardous Substances List (MA), Michigan Critical Substances List (MI), Minnesota
Hazardous Substances List (MN), New Jersey Right-to-Know List (NJ), New York Hazardous Substances List (NY),
Pennsylvania Right-to-Know List (PA), Washington Permissible Exposures List (WA), Wisconsin Hazardous Substances
List (WI).
15.8 Other Requirements:
The primary components of this product are not listed in Annex I of EU Directive 67/548/EEC.
Nickel Oxyhydroxide
: Harmful (Xn). Risk Phrases (R): 40-43 - Limited evidence of carcinogenic
effect. May cause sensitization by skin contact. Safety Phrases
(S): 36-60-61 Wear suitable
protective clothing. This material and its container must be disposed of as hazardous waste. Avoid
release to the environment. Refer to special instructions.
Potassium Hydroxide
: Corrosive (C). Risk Phrases (R): 22-43 - Harmful if swallowed. Causes
severe burns. Safety Phrases
(S): 26-36/37/39-45 - In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and
eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Sodium Hydroxide
: Corrosive (C). Risk Phrases (R): 22-43 - Harmful if swallowed. Causes severe
burns. Safety Phrases
(S): 26-36/37/39-45 - In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face
protection. In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
16. OTHER INFORMATION
16.1 Other Information:
DANGER! CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. HARMFUL IF SWALLOWED. Do not breathe
fumes/mist/vapour/spray. Wash hands and exposed skin areas with soap and warm water thoroughly after handling.
Avoid release to the environment. Wear protective gloves/eye protection. IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting. IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with
water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses if present and easy to do – continue rinsing. KEEP OUT OF REACH OF CHILDREN.
WARNING: Use only the specified chargers according to device manufacturer’s instructions. Do not open battery,
dispose of in fire or short circuit-may explode, leak or get hot causing personal injury. Caution: do not use if case is
cracked. NON-SPILLABLE BATTERY.
WARNING: This product contains a substance(s) known to the State of California to cause cancer, birth defects or other
reproductive harm.
16.2 Terms & Definitions:
See last page of this Safety Data Sheet.
16.3 Disclaimer:
This Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR §1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Harbor Freight
Tools USA, Inc.’s knowledge, the information contained herein is reliable and accurate as of this date; however,
accuracy, suitability or completeness is not guaranteed and no warranties of any type, either expressed or implied, are
provided. The information contained herein relates only to the specific product(s). If this product(s) is combined with
other materials, all component properties must be considered. Data may be changed from time to time. Be sure to
consult the latest edition.
16.4 Prepared for:
Harbor Freight Tools USA, Inc.
26541 Agoura Road
Calabasas, CA 91302 USA
Tel: +1 (805) 388-1000
http://www.harborfreight.com/
16.5 Prepared by:
ShipMate, Inc.
P.O. Box 787
Sisters, Oregon 97759-0787 USA
Tel: +1 (310) 370-3600
Fax: +1 (310) 370-5700
http://www.shipmate.com
SAFETY DATA SHEET
Page 6 of 6
HFT-97861
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 1.1 SDS Revision Date: 7/25/2015
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a SDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
CAS No. Chemical Abstract Service Number
EXPOSURE LIMITS IN AIR:
ACGIH American Conference on Governmental Industrial Hygienists
C Ceiling Limit
ES Exposure Standard (Australia)
IDLH Immediately Dangerous to Life and Health
OSHA U.S. Occupational Safety and Health Administration
PEL Permissible Exposure Limit
STEL Short-Term Exposure Limit
TLV Threshold Limit Value
TWA Time Weighted Average
FIRST AID MEASURES:
CPR Cardiopulmonary resuscitation - method in which a person whose heart has
stopped receives manual chest compressions and breathing to circulate blood
and provide oxygen to the body.
HMIS-III HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
0 Minimal Hazard
HEALTH
1 Slight Hazard
FLAMMABILITY
2 Moderate Hazard
PHYSICAL HAZARDS
3 Severe Hazard
PERSONAL PROTECTION
4 Extreme Hazard
PERSONAL PROTECTION RATINGS:
A
G
B
H
C
I
D
J
E
K
F
X
Consult your supervisor or SOPs fo
r
special handling directions.
Safety Glasses
Splash Goggles
Face Shield &
Protective Eyewear
Gloves
Boots
Synthetic Apron
Protective Clothing
& Full Suit
Dust Respirator
Full Face Respirator
Dust & Vapor Half-
Mask Respirator
Full Face
Respirator
Airline Hood/Mask
or SCBA
OTHER STANDARD ABBREVIATIONS:
ML Maximum Limit
mg/m3 milligrams per cubic meter
NA Not Available
ND Not Determined
NE Not Established
NF Not Found
NR No Results
ppm parts per million
SCBA Self-Contained Breathing Apparatus
NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
FLAMMABILITY LIMITS IN AIR:
Autoignition
Temperature
Minimum temperature required to initiate combustion in air with no other
source of ignition
LEL Lower Explosive Limit - lowest percent of vapor in air, by volume, that will
explode or ignite in the presence of an ignition source
UEL Upper Explosive Limit - highest percent of vapor in air, by volume, that will
explode or ignite in the presence of an ignition source
HAZARD RATINGS:
0 Minimal Hazard
1 Slight Hazard
2 Moderate Hazard
3 Severe Hazard
4 Extreme Hazard
ACD Acidic
ALK Alkaline
COR Corrosive
W Use No Water
OX Oxidizer
TREFOIL Radioactive
TOXICOLOGICAL INFORMATION:
LD
50
Lethal Dose (solids & liquids) which kills 50% of the exposed animals
s
LC
50
Lethal concentration (gases) which kills 50% of the exposed animal
ppm Concentration expressed in parts of material per million parts
TD
lo
Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
TD
lo
, LD
lo
, & LD
o
or
TC, TC
o
, LC
lo
, & LC
o
Lowest dose (or concentration) to cause lethal or toxic effects
IARC International Agency for Research on Cancer
NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
TL
m
Median threshold limit
log K
OW
or log K
OC
Coefficient of Oil/Water Distribution
REGULATORY INFORMATION:
WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
TC Transport Canada
EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
NOHSC National Occupational Health and Safety Commission (Australia)
NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
WGK Wassergefährdungsklassen (German Water Hazard Class)
HMIS-III National Paint & Coatings Association Hazardous Materials Identification System
WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION (WHMIS) SYSTEM:
Class A Class B Class C Class D1 Class D2 Class D3 Class E Class F
Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive
EC (67/548/EEC) INFORMATION:
C E F N O T Xi Xn
Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
CLP/GHS (1272/2008/EC) PICTOGRAMS:
GHS01 GHS02 GHS03 GHS04 GHS05 GHS06 GHS07 GHS08 GHS09
Explosive Flammable Oxidizer Pressurized Corrosive Toxic
Harmful
Irritating
Health
Hazard
Environ-
ment
